I get this question a LOT in the support forums. The most common symptom is that you have a SharePoint site that you logon to. Once logged on, you are able to browse around on the site and navigate freely, but when you attempt to open a document from a document library on the site, you are once again prompted for logon credentials before the Office app will open the document. The reason this happens is because the site in question is not configured as either a Trusted Site or a Local Intranet Site in your Internet Explorer credentials. The fix is quite simple:
At this point, you should be able to open documents without being prompted for a second login.
EnjoyC
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